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Could be worthwhile considering pyrodex as a propellant (no need for a black powder licence) and later on if it lives up to expectations go to the expense and "hoop jumping" of a black powder licence.
Regarding loads I would suggest contacting the Muzzle Loaders Association of Great Britain.
Make sure that whatever recommendations you get are for single round ball / smoothbore and not "shotgun" load, and start light and work up.
There is also the can of worms of licencing if your gun is on a shotgun cert!
Cheers
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