I may be wrong but I think there is a problem with the oily CO2 cartridges. If the second shot from a cold gun reads much slower than the first then you have to suspect something is wrong.
What happens is that on the first shot the bore is empty, on the second shot it is full of oily guck which comes out in front of the pellet in one solid lump and may trip the first optic before the pellet arrives.
The work around is to put something between the muzzle and the cb-625 entrance. Paper of masking tape works. The oily gunge cannot get through so the pellet arrives at clear optics.
You might fix it by simply increasing the separation between muzzle and chronoscope. A bit more can make a big difference because the guck will dissipate PDQ and cb-625 has a trick to discount muzzle blast.
If shooting through paper fails to improve things, there is always the possibility that your gun really is limp as a wet weekend