What is supposed to happen theory is not always found in practice after looking at a few hundred cases. The Webley is such a weak performer, I would say it does not have enough power to expand the piston head material by impact. Virtually all airgun manufacturers use polyurethane piston seals today. PTFE is used by a few people for replacements because it is a very easy material to machine. Polyurethane takes a bit of care and skill to machine, it is more suitable for moulding. I am continually changing PTFE capsule seals in air pistols. They are usually white and have squashed into an indentation well below the level of the piercer, causing a leak.
Baz