Plating would increase it's size, blueing not.
Not so much of a worry which is worn, in any case not all that much to do with the cylinder taper.
Is the gun accurate? If so, perhaps much ado about very little. I assume that there is some throat to the barrel to compensate for imperfect alignment of the tap, something (perfect alignment) that would be close to impossible to achieve using the production methods undoubtedly utilised. Only boring the tap through the barrel would achieve this and I seriously doubt that this was the way it was done.
It's only done on very few revolvers (same principle - boring cylinder through barrel) and the 95% that aren't still shoot straight.
Try a rod down the bore and try to feel for a step or lip of sorts at the tap, perhaps?
**WANTED**: WEBLEY PATRIOT MUZZLE END; Any Diana/Original mod.50 parts, especially OPEN SIGHTS